Kozicki professor of electrical engineering school of electrical, computer, and energy engineering, asu chief scientist, adesto technologies corp. The resistive switching in such memory device is attributed to electron transfer reaction between reduced graphene oxide sheets and thionine molecules. The customized approach exploits logic representations to synthesize for. Uses polysilicon fuses to connect the emitter of each bjt to the digital marx capital 1 pdf line. Resistive switching memory based on bioinspired natural. Resistance switching memories are memristors springerlink. We report on the conduction mechanisms of novel rumgocu and rumgota resistive switching memory rsm devices. All 2terminal nonvolatile memory devices based on resistance switching are memristors, regardless of the device material and physical operating mechanisms. Resistive switching memory and reconfigurable devices. This paper addresses the two main resistive switching rs memory technologies. Compared with an ionsbased rs, the observed rs behaviors have not shown the sharply switching feature but consecutively increasing. Cationbased resistive memory emerging nonvolatile memory technologies symposium san francisco bay area nanotechnology council april 6, 2012 michael n. Resistive switching memory based on bioinspired natural solid polymer electrolytes.
Resistive switching memories rrams are attractive for. Phasechange and redoxbased resistive switching memories. Reset statistics of niobased resistive switching memories. Subsequently, the system returns to hrs at a voltage v reset lower than v set. Resistive switching memories in mos2 nanosphere assemblies. Indepth understanding of resistive switching mechanism. The physical mechanism of resistive switching is generally attributed to the conductive filament made up of oxygen vacancies formation and rupture in the oxide due to field assisted oxygen ion migration. One step row readout technique and sensing circuitry mohammed e fouda, ahmed m. A resistive switching memory device consisting of reduced graphene oxide and indium tin oxide as topbottom two electrodes, separated by dielectric mos2 nanosphere assemblies as. It reduces the electric potential gradient, thus negatively affecting the functionality of resistive random access memory rram devices. Characterisation of novel resistive switching memory devices. Design and analysis of future memories based on switchable resistive elements. One of the most striking features of these devices is that they do not require a forming step, which is to be related to protrusions of the top electrode material inside the intrinsically porous.
In 2012 ieee international integrated reliability workshop final report, iirw 2012. The device shows nonvolatile resistive switching behaviors with an onoff ratio of more than 10 4, fast switching speed of 10 5 s, and good endurance. Resistive switching in polymer technische universiteit eindhoven. Resistive switching random access memories rram with simple metalinsulatormetal stacks are under intensive investigation owing to their great promise for use in nextgeneration memory applications 15. Logic synthesis for inmemory computing using resistive. Advances in resistive switching memories based on graphene. Pdf resistive switching memories based on metal oxides. This paper studies inmemory computing from two perspectives, i. Among the emerging memories, resistive switching memory rram raises strong interest due to its high speed, high density as a result of its simple twoterminal structure, and low cost of fabrication. A resistive switching rs phenomenon, namely reversible transitions between the low and high resistance states after forming process, is caused by the formation and rupture of a conductive filament.
Professor wei lu, chair assistant professor emmanouil kioupakis. Advances in resistive switching based memory devices sandeep munjal and neeraj khare1. Silicon compatible snbased resistive switching memory nanoscale. The resistance switching behaviour of several materials has recently attracted considerable attention for its application in nonvolatile memory nvm devices, popularly described as resistive random access memories rrams. Resistive hysteretic materials change their resistance. Appearance of quantum point contact in ptniopt resistive. Enhanced resistive switching memory characteristics and. Resistive switching memory integrated with amorphous. They all exhibit a distinctive fingerprint characterized by a pinched hysteresis loop confined to the first and the third quadrants of the v i plane whose contour shape in general changes with both the amplitude and frequency of any. Resistance switching memories are memristors nasaads. Pdf resistive switching memory based on bioinspired. However, details of the underlying microscopic behaviour of the resistive switching in rram are still largely missing.
Design and analysis of future memories based on switchable. Redoxbased resistive random access memory, or reram, is an emerging class of nanoelectronics elements which tend to rely upon filamentary behavior in order to realize multistate switching. Integration scheme of nanoscale resistive switching memory. They are subdivided into cationmigration cells, based on the electrochemical growth and dissolution of metallic filaments, and anionmigration cells, typically realized with transition metal oxides as the insulator, in which electronically conducting paths of suboxides are formed and removed. A, while few switching cycles are observed for wtao x. Yet another class of resistive switching phenomena is based on the electrically stimulated change of the resistance of a metalinsulator metal mim memory cell.
In this thesis, a defect probing technique based on the random telegraph noise rtn is developed for both filamentary and nonfilamentary devices, which can reveal the resistive switching mechanism at defect level and can also. Voltagetime dilemma of pure electronic mechanisms in resistive. They combine the advantages of flash and dram dynamic random access memories while avoiding their drawbacks, and they might be. Large banks of cheap, fast, nonvolatile, energy efficient, scalable solidstate memories are an increasingly essential component for todays data intensive. The carrier screening effect occurs commonly in dielectric materials.
In the following, an overv research work on conductivebridge memory metal oxide resistive switching memory oxr a reram cell is generally built by a cap insulatormetal mim structure, composed resistive material i sandwiched betwe conductors m as illustrated in fig. Resistive crossbar arrays enable denser memory due to the small size of switching. In this work, we present symmetric metalinsulatormetal bipolar memristors based on roomtemperature deposition of charged titaniumoxide nanoparticles formed in vacuum by a physical process. Resistive switching random access memory materials, device, interconnects, and scaling considerations. Overcoming the voltagetime dilemma of electrochemical metallization memories. Conduction mechanisms on high retention annealed mgobased. We also include in this report patent related to memristor. The value of v reset63% is roughly independent of r on while i reset63% increases with 1 r on. Nonpolar resistive memory switching with all four possible. However, the tao x based rram devices with prospective and challenges. Highperformance hfoxaloybased resistive switching memory. Nanoionicsbased resistive switching memories request pdf. Resistance switching memories are memristors 767 fig.
Nanoionicsbased resistive switching memories dante r. Department of electrical engineering boise state university 1910 university dr. One of the first reported polymer based resistive switching memory. Resistive switching memory and reconfigurable devices by jiantao zhou a dissertation submitted in partial fulfillment of the requirements for the degree of doctor of philosophy electrical engineering in the university of michigan 2016 doctoral committee. Advances in resistive switching memories based on graphene oxide. Organic resistive memory university of nebraskalincoln. Nanoionicsbased resistive switching memories nature. Resistive switching random access memory materials. Sorry, we are unable to provide the full text but you may find it at the following locations. Nonvolatile resistive switching memoriescharacteristics.
Polymerbased resistive memories good scalability, flexibility, low cost, ease of processing, 3dstacking. Resistive switching memory for nonvolatile storage and. Unlike modern semiconductor memory devices, needless to say, human memory is by no means eternal. Recent progress in resistive switching memories yoshio nishi stanford university stanford, california u. The memory device shows reproducible and reliable bipolar resistive switching characteristics. The memory effect is based on resistive switching mechanisms that can be explained through the creation and destruction of conductive filaments in devices with metalinsulatormetal mim. Resistive memories should not necessarily be made completely from new. A system in its highresistance state off is switched set by a threshold voltage into the lowresistance state on as sketched in fig. Memory is an essential building block in learning and decisionmaking in biological systems. The experimental observations show that the weibull slopes of both v reset and i reset cumulative distributions increase linearly with 1 r on.
They all exhibit a distinctive fingerprint characterized by a pinched hysteresis loop confined to the first and the third quadrants of the vi plane whose contour shape in general changes with both the amplitude and frequency of. Katiyar1 1department of physics and institute for functional nanomaterials, university of puerto rico, san juan, pr009368377, usa. Highperformance hfoxaloybased resistive switching memory crosspoint array fabricated by atomic layer deposition. Combined with the inherent scalability of the resistive switching memory rram, where the switching region consists of a conductive filament as small as a single atom, nws may provide an ideal approach to reduce the device area to a range not accessible to conventional lithography. This device exhibits the rewritable nonvolatile resistive switching with low setreset voltage.
A novel resistive random access memory device is designed with srtio3 la23srmno3 lsmomgal2o4 maocu structure, in which metallic epitaxial lsmo is employed as the bottom electrode rather. His research group investigates emerging device technologies, such as phase change memory pcm and resistive switching memory reram for both memory and computing applications. We confirmed that conductive filaments including a quantum point contact qpc in pt niopt rs cells were formed by semiforming, the first step of the forming process. Rram is a type of nvm that uses a materials that changes the resistance when a voltage is applied. As a model system for device physics study, hfox based rram devices were fabricated and characterized. The author explains the physics of the devices and provides a concrete description of the materials involved as well as the fundamental. He has authored six book chapters, more than 200 papers published in international journals and presented at international conferences, and four patents to his name.
In unipolar rram, the switching direction does not depend on the polarity of the applied voltage. Lowenergy resistive random access memory devices with no. As it can be seen, the device switches from hrs to lrs at a high voltage v set. Publishers pdf, also known as version of record includes final page. A memory device based on natural organic material is a promising device toward the next generation of nonvolatile nanoelectronics. We fabricated cu 2 obased nanoscale memory devices using 250nm viahole structures on silicon wafers. Shortterm memory to longterm memory transition in a. A solutionprocessed, chitosanbased resistiveswitching memory device is demonstrated with ptagdoped chitosanag structure. Memories in digital electronics pdf 5 digital circuitry page 1 of 21. They combine the advantages of flash and dram dynamic random access memories while avoiding their drawbacks, and they might be highly scalable. The three main classes are based on an electrochemical metallization mechanism, a valence change mechanism, and a thermochemical mechanism, respectively. Many metalinsulatormetal systems show electrically induced resistive switching effects and have therefore been proposed as the basis for future nonvolatile memories. Emerging resistive switching memories jianyong ouyang.
A resistive switching memory device consisting of reduced graphene oxide and indium tin oxide as topbottom two electrodes, separated by dielectric mos 2 nanosphere assemblies as the active interlayer, was fabricated. Eltawil, senior member, ieee, and fadi kurdahi, fellow, ieee abstracttransistorbased memories are rapidly approaching their maximum density per unit area. Inmemory computing with resistive switching devices. Yet, forgetfulness is not always a disadvantage since it releases memory storage for more important or more frequently accessed pieces of information and is thought to be necessary for individuals to. Organic resistive memory polymers, organic smallmolecule compounds, and inorganicorganic hybrid yuewei yin xus group meeting 02122016. The cu 2 o as the resistive switching layer of nanoscale memory devices was deposited using ecd. In this letter, we present the characterization and modeling of the reset statistics of ptniow resistive random access memories. Advances in resistive switching based memory devices. An auzno filmaldoped zno device fabricated in this work exhibited no resistive switching rs. This report does not include patents related to resistive switching such as phase change random access memories and magnetic random access memories, but also ferroelectric random access memories. Switching is called unipolar or symmetric when the switching procedure does not depend on the polarity of the voltage and current signal.